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Stosur reached her first WTA Tour final at her home event in Gold Coast, losing to Patty Schnyder.She was runner-up at the Sydney event, defeating by walkover the world No. In 2006, she represented Australia alongside Todd Reid at the Hopman Cup, winning all of her singles matches.
At the Medibank International, she was defeated by top-seed Serena Williams in a close three-set match.
In 2002, she lost in the first round at the Gold Coast event. She reached the second round of the Moorilla Hobart International, then the second round of the Australian Open, and later qualified for WTA events in Acapulco, Indian Wells, Vienna and Birmingham.
In 2003, Stosur won her first WTA singles matches, reaching the third round of the Australian Open. Stosur competed at the Athens Olympics, where she lost in the first round.
Seeded fourth in doubles, the pair of Stosur and Rennae Stubbs lost to Peng Shuai and Hsieh Su-wei in the first round of the tournament.
Stosur defeated Klára Zakopalová and Sabine Lisicki before losing in the third round to world No. She also won through to the third round in doubles, partnering Stubbs, defeating the Radwańska sisters.In 2000, she debuted at the Australian Open losing in the first qualifying round.